Activation, Deactivation, and Poisoning of Catalysts by John B. Butt

By John B. Butt

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Woody Allen The approach to be taken here is largely an extension of that used by catalytic chemists endeavoring to understand a reaction taking place on a heterogeneous catalyst. , the detailed path) that the molecules follow during reaction, and finally to measure the rates at which the various reactions occur. If, in addition, the deactivation characteristics of the catalyst are to be studied, then an effort of a similar nature is needed to identify the reactions causing deactivation, to learn the detailed manner in which these reactions interact with the main reaction, and to measure the rates of the deactivating reactions.

J. J. Berzelius, Ann. Chem. Phys. 61, 146 (1836). 4. M. Boudart, Chem. Eng. Prog. 57, 33 (1961). 5. R. L. , ACS Symp. Ser. No. 222, 3 (1983). 6. J. B. Butt, AIChEJ. 22, 1 (1976). 26 1. Physical and Chemical Description of Deactivation 7. 8. 9. 10. J. J. , p. 124 (1974). M. Faraday, Philos. Trans. R. Soc. London. 124, 55 (1834). S. Fuentes and J. C. S. S. Faraday I 74, 174 (1978). S. J. Gregg and K. S. W. " Academic Press, New York, 1967. W. B. Innes, in "Experimental Methods in Catalysis Research" (R.

I want to be immortal by not dying. Woody Allen The approach to be taken here is largely an extension of that used by catalytic chemists endeavoring to understand a reaction taking place on a heterogeneous catalyst. , the detailed path) that the molecules follow during reaction, and finally to measure the rates at which the various reactions occur. If, in addition, the deactivation characteristics of the catalyst are to be studied, then an effort of a similar nature is needed to identify the reactions causing deactivation, to learn the detailed manner in which these reactions interact with the main reaction, and to measure the rates of the deactivating reactions.

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